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An Indian Express report quoted her as saying, wisest decision I made at the age of 24 was to become a mother. It stabilised my life. People think it was a great act of charity and wonderful action but it was self preservation. So the debate to whether you need to pop and remove pimples is still well opened. But for me, I think that squeezing and popping out the pimples is not a shortcut to get rid of them. When you intentionally open them, you will irritate your skin and delay the healing much more because you would have already created a small hole in your skin..
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The synthesis and determination of the pKa values of bis 0 proline and bis L proline diketopiperazine are described. Values for kHo (M 1s 1), the second order rate constant for deprotonation at the a carbon of the OKP were determined as described above. Evidence is presented that the reverse rate of protonation of the OKP enolates by solvent water is likely to be less than diffusion controlled.
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